A silyl radical formed by muonium addition to a silylene

Amitabha Mitra; Jean Claude Brodovitch; Clemens Krempner; Paul W. Percival; Pooja Vyas; Robert West

doi:10.1002/anie.201000166

A silyl radical formed by muonium addition to a silylene

Amitabha Mitra, Jean Claude Brodovitch, Clemens Krempner, Paul W. Percival, Pooja Vyas, Robert West

Chemistry and Biochemistry

Research output: Contribution to journal › Article › peer-review

30 Scopus citations

Abstract

(Figure Presented) Muonraker: Irradiation of the stable silylene N,N'-bis(2,6-diisopropylphenyl)-l,3diaza-2-silacyclopent-4-en-2-ylidene with muons produced a radical that was identified as the monomeric muonium adduct from its muon spin rotation (μSR) spectrum. The muon hyperfine constant for this radical is 931 MHz, the largest ever recorded for a free radical.

Original language	English
Pages (from-to)	2893-2895
Number of pages	3
Journal	Angewandte Chemie - International Edition
Volume	49
Issue number	16
DOIs	https://doi.org/10.1002/anie.201000166
State	Published - Apr 6 2010

Keywords

Disilanes
Muonium
Radicals
Silylenes

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title = "A silyl radical formed by muonium addition to a silylene",

abstract = "(Figure Presented) Muonraker: Irradiation of the stable silylene N,N'-bis(2,6-diisopropylphenyl)-l,3diaza-2-silacyclopent-4-en-2-ylidene with muons produced a radical that was identified as the monomeric muonium adduct from its muon spin rotation (μSR) spectrum. The muon hyperfine constant for this radical is 931 MHz, the largest ever recorded for a free radical.",

keywords = "Disilanes, Muonium, Radicals, Silylenes",

author = "Amitabha Mitra and Brodovitch, {Jean Claude} and Clemens Krempner and Percival, {Paul W.} and Pooja Vyas and Robert West",

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T1 - A silyl radical formed by muonium addition to a silylene

AU - Mitra, Amitabha

AU - Brodovitch, Jean Claude

AU - Krempner, Clemens

AU - Percival, Paul W.

AU - Vyas, Pooja

AU - West, Robert

PY - 2010/4/6

Y1 - 2010/4/6

N2 - (Figure Presented) Muonraker: Irradiation of the stable silylene N,N'-bis(2,6-diisopropylphenyl)-l,3diaza-2-silacyclopent-4-en-2-ylidene with muons produced a radical that was identified as the monomeric muonium adduct from its muon spin rotation (μSR) spectrum. The muon hyperfine constant for this radical is 931 MHz, the largest ever recorded for a free radical.

AB - (Figure Presented) Muonraker: Irradiation of the stable silylene N,N'-bis(2,6-diisopropylphenyl)-l,3diaza-2-silacyclopent-4-en-2-ylidene with muons produced a radical that was identified as the monomeric muonium adduct from its muon spin rotation (μSR) spectrum. The muon hyperfine constant for this radical is 931 MHz, the largest ever recorded for a free radical.

KW - Disilanes

KW - Muonium

KW - Radicals

KW - Silylenes

UR - http://www.scopus.com/inward/record.url?scp=77950513660&partnerID=8YFLogxK

U2 - 10.1002/anie.201000166

DO - 10.1002/anie.201000166

M3 - Article

C2 - 20229560

AN - SCOPUS:77950513660

SN - 1433-7851

VL - 49

SP - 2893

EP - 2895

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 16

ER -

A silyl radical formed by muonium addition to a silylene

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Keywords

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