A silyl radical formed by muonium addition to a silylene

Amitabha Mitra, Jean Claude Brodovitch, Clemens Krempner, Paul W. Percival, Pooja Vyas, Robert West

Research output: Contribution to journalArticle

23 Scopus citations

Abstract

(Figure Presented) Muonraker: Irradiation of the stable silylene N,N'-bis(2,6-diisopropylphenyl)-l,3diaza-2-silacyclopent-4-en-2-ylidene with muons produced a radical that was identified as the monomeric muonium adduct from its muon spin rotation (μSR) spectrum. The muon hyperfine constant for this radical is 931 MHz, the largest ever recorded for a free radical.

Original languageEnglish
Pages (from-to)2893-2895
Number of pages3
JournalAngewandte Chemie - International Edition
Volume49
Issue number16
DOIs
StatePublished - Apr 6 2010

Keywords

  • Disilanes
  • Muonium
  • Radicals
  • Silylenes

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