A novel electrophilic diamination reaction of alkenes

Guigen Li; Han Xun Wei; Sun Hee Kim; Michael D. Carducci

doi:10.1002/1521-3773(20011119)40:22<4277::AID-ANIE4277>3.0.CO;2-I

A novel electrophilic diamination reaction of alkenes

Guigen Li, Han Xun Wei, Sun Hee Kim, Michael D. Carducci

Chemistry and Biochemistry

Research output: Contribution to journal › Article › peer-review

147 Scopus citations

Abstract

A three-component electrophilic reaction transforms olefins into imidazoline and diamine derivatives (see scheme). Rhodium(II) heptafluorobutyrate dimer (2 mol%) was utilized as the catalyst and N,N-dichloro-p-toluenesulfonamide (TsNCl₂) and acetonitrile as the nitrogen sources. Modest to good yields (45-82%) and high regio- and stereoselectivity were achieved.

Original language	English
Pages (from-to)	4277-4280
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	40
Issue number	22
DOIs	https://doi.org/10.1002/1521-3773(20011119)40:22<4277::AID-ANIE4277>3.0.CO;2-I
State	Published - Nov 19 2001

Keywords

Amination
Electrophilic additions
Homogeneous catalysis
Nitrogen heterocycles
Rhodium

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10.1002/1521-3773(20011119)40:22<4277::AID-ANIE4277>3.0.CO;2-I

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AU - Carducci, Michael D.

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KW - Amination

KW - Electrophilic additions

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