A local composition model for the excess Gibbs energy of aqueous electrolyte systems

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Abstract

The electrolyte nonrandom two‐liquid (NRTL) model proposed by Chen et al. (1982) is generalized to represent the excess Gibbs energy of aqueous multicomponent electrolyte systems. Using only binary parameters, the model correlates and predicts the deviation from ideality of aqueous multicomponent electrolyte systems over the entire range of temperature and concentration.

Original languageEnglish
Pages (from-to)444-454
Number of pages11
JournalAIChE Journal
Volume32
Issue number3
DOIs
StatePublished - Mar 1986

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