Abstract
A combined inelastic neutron scattering (INS) and theoretical study of H2 sorption in Y-FTZB, a recently reported metal-organic framework (MOF) with fcu topology, reveals that the strongest binding site in the MOF causes a high barrier to rotation on the sorbed H2. This rotational barrier for H2 is the highest yet of reported MOF materials based on physisorption.
Original language | English |
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Pages (from-to) | 14109-14112 |
Number of pages | 4 |
Journal | Chemical Communications |
Volume | 50 |
Issue number | 91 |
DOIs | |
State | Published - Oct 21 2014 |