A high rotational barrier for physisorbed hydrogen in an fcu-metal-organic framework

Tony Pham, Katherine A. Forrest, Peter A. Georgiev, Wiebke Lohstroh, Dong Xu Xue, Adam Hogan, Mohamed Eddaoudi, Brian Space, Juergen Eckert

Research output: Contribution to journalArticle

23 Scopus citations

Abstract

A combined inelastic neutron scattering (INS) and theoretical study of H2 sorption in Y-FTZB, a recently reported metal-organic framework (MOF) with fcu topology, reveals that the strongest binding site in the MOF causes a high barrier to rotation on the sorbed H2. This rotational barrier for H2 is the highest yet of reported MOF materials based on physisorption.

Original languageEnglish
Pages (from-to)14109-14112
Number of pages4
JournalChemical Communications
Volume50
Issue number91
DOIs
StatePublished - Oct 21 2014

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    Pham, T., Forrest, K. A., Georgiev, P. A., Lohstroh, W., Xue, D. X., Hogan, A., Eddaoudi, M., Space, B., & Eckert, J. (2014). A high rotational barrier for physisorbed hydrogen in an fcu-metal-organic framework. Chemical Communications, 50(91), 14109-14112. https://doi.org/10.1039/c4cc05987e