A catalytic synthesis of aziridines without the usual byproducts

Arindam Mazumdar; Zheng Xue; Michael F. Mayer

doi:10.1055/s-2007-984872

A catalytic synthesis of aziridines without the usual byproducts

Arindam Mazumdar, Zheng Xue, Michael F. Mayer

Chemistry and Biochemistry

Research output: Contribution to journal › Article › peer-review

15 Scopus citations

Abstract

Complementary to existing routes, the Lewis acid catalyzed reactions of phenyldiazomethane with α-imino esters selectively produce cis-aziridine-2-carboxylates without competitive formation of enamino ester or carbene dimer byproducts.

Original language	English
Pages (from-to)	2025-2028
Number of pages	4
Journal	Synlett
Issue number	13
DOIs	https://doi.org/10.1055/s-2007-984872
State	Published - Aug 13 2007

Keywords

Catalysis
Diazo compounds
Heterocycles
Imines
Lewis acids

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title = "A catalytic synthesis of aziridines without the usual byproducts",

abstract = "Complementary to existing routes, the Lewis acid catalyzed reactions of phenyldiazomethane with α-imino esters selectively produce cis-aziridine-2-carboxylates without competitive formation of enamino ester or carbene dimer byproducts.",

keywords = "Catalysis, Diazo compounds, Heterocycles, Imines, Lewis acids",

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AU - Mazumdar, Arindam

AU - Xue, Zheng

AU - Mayer, Michael F.

PY - 2007/8/13

Y1 - 2007/8/13

N2 - Complementary to existing routes, the Lewis acid catalyzed reactions of phenyldiazomethane with α-imino esters selectively produce cis-aziridine-2-carboxylates without competitive formation of enamino ester or carbene dimer byproducts.

AB - Complementary to existing routes, the Lewis acid catalyzed reactions of phenyldiazomethane with α-imino esters selectively produce cis-aziridine-2-carboxylates without competitive formation of enamino ester or carbene dimer byproducts.

KW - Catalysis

KW - Diazo compounds

KW - Heterocycles

KW - Imines

KW - Lewis acids

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U2 - 10.1055/s-2007-984872

DO - 10.1055/s-2007-984872

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SP - 2025

EP - 2028

JO - Synlett

JF - Synlett

IS - 13

ER -

A catalytic synthesis of aziridines without the usual byproducts

Abstract

Keywords

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