2-Quinoxalinol diamine Cu (II) complex: facilitating catalytic oxidation through dual mechanisms

Yuancheng Li; TaeBum Lee; Kushan Weerasiri; Tanyu Wang; Emily E Buss; Michael L McKee; Anne Gorden

doi:10.1039/C4DT01562B

2-Quinoxalinol diamine Cu (II) complex: facilitating catalytic oxidation through dual mechanisms

Yuancheng Li, TaeBum Lee, Kushan Weerasiri, Tanyu Wang, Emily E Buss, Michael L McKee, Anne Gorden

Chemistry and Biochemistry

Research output: Contribution to journal › Article › peer-review

Abstract

The Cu(II) complex 1, Cu(II)-6-N-3,5-di-tert-butylsalicylidene-6,7-quinoxalinol-diamine, has been developed to address problems with current methods of catalytic oxidation using tert-butyl hydroperoxide (TBHP). Complex 1 demonstrated an increased capability to utilize TBHP while limiting interference from free radical reactions and was demonstrated to be highly effective in the oxidations of a variety of olefins.

Original language	English
Pages (from-to)	13578--13583
Journal	Dalton Transactions
DOIs	https://doi.org/10.1039/C4DT01562B
State	Published - 2014

Access to Document

10.1039/C4DT01562B

Cite this

@article{2cd0a6629dcb4df6aa4686990b27d844,

title = "2-Quinoxalinol diamine Cu (II) complex: facilitating catalytic oxidation through dual mechanisms",

abstract = "The Cu(II) complex 1, Cu(II)-6-N-3,5-di-tert-butylsalicylidene-6,7-quinoxalinol-diamine, has been developed to address problems with current methods of catalytic oxidation using tert-butyl hydroperoxide (TBHP). Complex 1 demonstrated an increased capability to utilize TBHP while limiting interference from free radical reactions and was demonstrated to be highly effective in the oxidations of a variety of olefins.",

author = "Yuancheng Li and TaeBum Lee and Kushan Weerasiri and Tanyu Wang and Buss, {Emily E} and McKee, {Michael L} and Anne Gorden",

year = "2014",

doi = "10.1039/C4DT01562B",

language = "English",

pages = "13578----13583",

journal = "Dalton Transactions",

publisher = "Royal Society of Chemistry",

}

TY - JOUR

T1 - 2-Quinoxalinol diamine Cu (II) complex: facilitating catalytic oxidation through dual mechanisms

AU - Li, Yuancheng

AU - Lee, TaeBum

AU - Weerasiri, Kushan

AU - Wang, Tanyu

AU - Buss, Emily E

AU - McKee, Michael L

AU - Gorden, Anne

PY - 2014

Y1 - 2014

N2 - The Cu(II) complex 1, Cu(II)-6-N-3,5-di-tert-butylsalicylidene-6,7-quinoxalinol-diamine, has been developed to address problems with current methods of catalytic oxidation using tert-butyl hydroperoxide (TBHP). Complex 1 demonstrated an increased capability to utilize TBHP while limiting interference from free radical reactions and was demonstrated to be highly effective in the oxidations of a variety of olefins.

AB - The Cu(II) complex 1, Cu(II)-6-N-3,5-di-tert-butylsalicylidene-6,7-quinoxalinol-diamine, has been developed to address problems with current methods of catalytic oxidation using tert-butyl hydroperoxide (TBHP). Complex 1 demonstrated an increased capability to utilize TBHP while limiting interference from free radical reactions and was demonstrated to be highly effective in the oxidations of a variety of olefins.

U2 - 10.1039/C4DT01562B

DO - 10.1039/C4DT01562B

M3 - Article

SP - 13578

EP - 13583

JO - Dalton Transactions

JF - Dalton Transactions

ER -

2-Quinoxalinol diamine Cu (II) complex: facilitating catalytic oxidation through dual mechanisms

Abstract

Access to Document

Fingerprint

Cite this